Tuning of spin crossover equilibrium in catecholatoiron(III) complexes by supporting ligands.

نویسندگان

  • Yutaka Hitomi
  • Masakazu Higuchi
  • Hisataka Minami
  • Tsunehiro Tanaka
  • Takuzo Funabiki
چکیده

Introduction of electron-withdrawing groups on co-ligands effectively raises the spin crossover temperature of catecholatoiron(III) complexes and induces a significant amount of the low spin species in solution even at around room temperature.

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عنوان ژورنال:
  • Chemical communications

دوره 13  شماره 

صفحات  -

تاریخ انتشار 2005